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[Hederagonic acid (23-hydroxy-3-oxo-olean-12-en-28-oic acid) (1) is a naturally occurring pentacyclic triterpenoid based on the oleanane scaffold (Figure 1.1). The molecule is related to hederagenin (2), found in Hedera helix (common ivy). Hederagonic acid (1) can in principle be accessed from...
[Hederagonic acid was found to be a suitable starting material for the synthesis of polyhydroxylated triterpenoids. Nevertheless, hederagonic acid is very expensive and has limited commercial availability. Hederagonic acid can be synthetically accessed from oleanolic acid, a cheap and readily...
[Glassware and Techniques: Unless otherwise indicated, no glassware was flame dried before use, and all reactions were performed under an air atmosphere, not using standard Schlenk-techniques. Reagents and Solvents: Unless otherwise stated, all reagents and solvents were used as received from...
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