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Chlorine atom-initiated photooxidations of CH2FCF3 (HFC-134a) in O2-N2 diluent were carried out to identify the products formed from the
$$CF_3 CHF\dot O$$
radical reactions and to determine the product yields as a function of temperature, pressure and O2 concentration. CF3C(O)F and HC(O)F...
We present simultaneous field measurements of NO3 and peroxy radicals made at night in a forested area (Schauinsland, Black Forest, 48° N, 8° N, 1150 ASL), together with measurements of CO, O3, NO
, and hydrocarbons, as well as meteorological parameters. NO2, NO3, HO2, and ∑(RO2)...
Rate constants for the gas-phase reactions of OH radicals with nopinone (6,6-dimethylbicyclo[3.1.1]heptan-2-one) and camphenilone (3,3-dimethylbicyclo[2.2.1]heptan-2-one) and for the reactions of 4-acetyl-1-methylcyclohexene with OH and NO3 radicals and O3 have been measured at 296±2 K. The rate...
Several mono- and bifunctional organic nitrates of atmospheric interest were prepared in a one-step synthesis, based on the reaction of alcohols with N2O5 (dinitrogen pentoxide) at low temperatures. The method is well suitable for micro-scale preparations. The compounds were characterized by...
The presence of amino acids in atmospheric precipitation and aerosols has been noted for many years, yet relatively little is known about these or other nitrogen containing organic compounds in the atmosphere. Marine and continental rainwater analyses indicate that atmospheric aerosols, and...
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