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As in previous years, this review will emphasise synthetic, structural and spectroscopic aspects of discrete molecular species containing Group 16 elements. Notable advances include the increasing prominence of organochalcogen-nitrogen heterocycles for materials applications and the wealth of...
The highlights of this years literature include the discovery of new supramolecular halogen bonding motifs, an efficient one-step synthesis of RIF 2 and RI(OAc) 2 compounds using Selectfluor, and new perspectives on the fluxional behaviour of XeF 6 .
In copper( i ) chemistry, ‘CuH in a bottle’ is noteworthy, as is a rare example of CO and perchlorate in the same coordination sphere. Geochemists will be interested in the observation of oxygen exchange between sulfate and non-coordinated water in CuSO 4 ·5H 2 O. In copper( ii ) chemistry, the...
The development of new synthetic routes and instrumentation for characterisation have resulted in a number of outstanding publications in 2005. The increasing use of elevated pressure, combined with in situ diffraction techniques, has resulted in the identification of a new phase of elemental...
In the area of Li ion cells, highlights have included the observation of a solid solution Li x FePO 4 at elevated temperatures by Delacourt et al . and further studies of the new promising phosphate fluoride cathode, LiVPO 4 F, by Barker et al . In the area of solid oxide fuel cells/oxide ion...
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