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Commission on Spin, Charge and Momentum Density. Project No. 1. Standardization of Compton profile measurements - The Compton profile of water

Commission on Spin, Charge and Momentum Density. Project No. 1. Standardization of Compton... Thirteen measurements of the Compton profile of water carried out in five different laboratories are compared. The possible sources of error inherent in Compton measurements are analysed. Inconsistent normalization of the various profiles is found to be an important source of error. After renormalization of the profiles the results are found to be consistent to within plus or minus 2% of the peak height of the profiles. It is shown that all probable sources of error can be analysed in terms of five general types of error and further that the effects of all of these types of error on the shape of the Compton profile are almost indistinguishable from one another. The determination of the position of the Compton peak is found to be another important potential source of error in experimental measurements. Certain assumptions relating to the conversion to a momentum scale were found to be mistaken and are corrected. A comparison of currently accepted relativistic and non-relativistic expressions for the cross section revealed that they are not in fact significantly different. Multiple scattering is found to be the only major source of error which is not yet well understood. Each experimental measurement is assessed in detail with particular regard to the differences between the techniques used by the contributing groups. Proposals are made relating to the accumulation, processing and presentation of Compton data. It is concluded that a reproducibility of plus or minus 1% of the peak height of the profile is quite feasible and that in a differential experiment plus or minus 0.5% or even better is possible. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Acta Crystallographica Section A: Crystal Physics, Diffraction, Theoretical and General Crystallography International Union of Crystallography

Commission on Spin, Charge and Momentum Density. Project No. 1. Standardization of Compton profile measurements - The Compton profile of water

Commission on Spin, Charge and Momentum Density. Project No. 1. Standardization of Compton profile measurements - The Compton profile of water


Abstract

Thirteen measurements of the Compton profile of water carried out in five different laboratories are compared. The possible sources of error inherent in Compton measurements are analysed. Inconsistent normalization of the various profiles is found to be an important source of error. After renormalization of the profiles the results are found to be consistent to within plus or minus 2% of the peak height of the profiles. It is shown that all probable sources of error can be analysed in terms of five general types of error and further that the effects of all of these types of error on the shape of the Compton profile are almost indistinguishable from one another. The determination of the position of the Compton peak is found to be another important potential source of error in experimental measurements. Certain assumptions relating to the conversion to a momentum scale were found to be mistaken and are corrected. A comparison of currently accepted relativistic and non-relativistic expressions for the cross section revealed that they are not in fact significantly different. Multiple scattering is found to be the only major source of error which is not yet well understood. Each experimental measurement is assessed in detail with particular regard to the differences between the techniques used by the contributing groups. Proposals are made relating to the accumulation, processing and presentation of Compton data. It is concluded that a reproducibility of plus or minus 1% of the peak height of the profile is quite feasible and that in a differential experiment plus or minus 0.5% or even better is possible.

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References (2)

Publisher
International Union of Crystallography
Copyright
Copyright (c) 1976 International Union of Crystallography
ISSN
0567-7394
DOI
10.1107/S0567739476001149
Publisher site
See Article on Publisher Site

Abstract

Thirteen measurements of the Compton profile of water carried out in five different laboratories are compared. The possible sources of error inherent in Compton measurements are analysed. Inconsistent normalization of the various profiles is found to be an important source of error. After renormalization of the profiles the results are found to be consistent to within plus or minus 2% of the peak height of the profiles. It is shown that all probable sources of error can be analysed in terms of five general types of error and further that the effects of all of these types of error on the shape of the Compton profile are almost indistinguishable from one another. The determination of the position of the Compton peak is found to be another important potential source of error in experimental measurements. Certain assumptions relating to the conversion to a momentum scale were found to be mistaken and are corrected. A comparison of currently accepted relativistic and non-relativistic expressions for the cross section revealed that they are not in fact significantly different. Multiple scattering is found to be the only major source of error which is not yet well understood. Each experimental measurement is assessed in detail with particular regard to the differences between the techniques used by the contributing groups. Proposals are made relating to the accumulation, processing and presentation of Compton data. It is concluded that a reproducibility of plus or minus 1% of the peak height of the profile is quite feasible and that in a differential experiment plus or minus 0.5% or even better is possible.

Journal

Acta Crystallographica Section A: Crystal Physics, Diffraction, Theoretical and General CrystallographyInternational Union of Crystallography

Published: May 1, 1976

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