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LaRCTM-IA, the polyimide prepared with 3,4′-oxydianiline (3,4′-ODA) and oxydiphthalic anhydride (ODPA), is useful as a film, coating, adhesive, and composite matrix. The high temperature capability and fire-resistance of polyimides also makes them attractive candidates for textile fibers for a variety of uses in the automotive, chemical, and aerospace industries. This research describes for the first time the melt-spinning of phthalic anhydride endcapped LaRCTM-IA and the effects of processing conditions on the mechanical properties of slightly-drawn fibers. Average draw ratios varied from 1 to 3.9. Tensile strengths ranged from 103 to 159 MPa; moduli ranged from 2.80 to 3.21 GPa; elongations at break ranged from 14 to 103%. For comparison, tensile properties of compression-molded films prepared at the same temperatures are also reported. Melt-extruded fibers and melt-pressed films of another thermoplastic, ULTEM®, were also fabricated. ULTEM® fibers exhibited tensile strengths ranging from 138 to 207 MPa for average draw ratios of 4.5 to 10.3. Moduli ranged from 2.70 to 3.22 GPa. Elongations at break ranged from 47 to 111%.
Advanced Performance Materials – Springer Journals
Published: Oct 1, 2004
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