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Recent advances in antimony removal using carbon-based nanomaterials: A review

Recent advances in antimony removal using carbon-based nanomaterials: A review Recently, special attention has been deserved to environmental risks of antimony (Sb) element that is of highly physiologic toxicity to human. Conventional coagulation and ion exchange methods for Sb removal are faced with challenges of low efficiency, high cost and secondary pollution. Adsorption based on carbon nanomaterials (CNMs; e.g., carbon nanotubes, graphene, graphene oxide, reduced graphene oxide and their derivatives) may provide effective alternative because the CNMs have high surface area, rich surface chemistry and high stability. In particular, good conductivity makes it possible to create linkage between adsorption and electrochemistry, thereby the synergistic interaction will be expected for enhanced Sb removal. This review article summarizes the state of art on Sb removal using CNMs with the form of nano-adsorbents and/or filtration membranes. In details, procedures of synthesis and functionalization of different forms of CNMs were reviewed. Next, adsorption behavior and the underlying mechanisms toward Sb removal using various CNMs were presented as resulting from a retrospective analysis of literatures. Last, we prospect the needs for mass production and regeneration of CNMs adsorbents using more affordable precursors and objective assessment of environmental impacts in future studies.[graphic not available: see fulltext] http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Frontiers of Environmental Science & Engineering Springer Journals

Recent advances in antimony removal using carbon-based nanomaterials: A review

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References (99)

Publisher
Springer Journals
Copyright
Copyright © Higher Education Press 2021
ISSN
2095-2201
eISSN
2095-221X
DOI
10.1007/s11783-021-1482-7
Publisher site
See Article on Publisher Site

Abstract

Recently, special attention has been deserved to environmental risks of antimony (Sb) element that is of highly physiologic toxicity to human. Conventional coagulation and ion exchange methods for Sb removal are faced with challenges of low efficiency, high cost and secondary pollution. Adsorption based on carbon nanomaterials (CNMs; e.g., carbon nanotubes, graphene, graphene oxide, reduced graphene oxide and their derivatives) may provide effective alternative because the CNMs have high surface area, rich surface chemistry and high stability. In particular, good conductivity makes it possible to create linkage between adsorption and electrochemistry, thereby the synergistic interaction will be expected for enhanced Sb removal. This review article summarizes the state of art on Sb removal using CNMs with the form of nano-adsorbents and/or filtration membranes. In details, procedures of synthesis and functionalization of different forms of CNMs were reviewed. Next, adsorption behavior and the underlying mechanisms toward Sb removal using various CNMs were presented as resulting from a retrospective analysis of literatures. Last, we prospect the needs for mass production and regeneration of CNMs adsorbents using more affordable precursors and objective assessment of environmental impacts in future studies.[graphic not available: see fulltext]

Journal

Frontiers of Environmental Science & EngineeringSpringer Journals

Published: Apr 1, 2022

Keywords: Antimony; Carbon nanomaterials; Adsorption; Membrane separation

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