Access the full text.
Sign up today, get DeepDyve free for 14 days.
Loading next page...
/lp/wiley/electrochemical-reduction-of-nitrates-on-coo-nanoclusters-6VToi33h2g
References (64)
-
M. Ahmed, Chuangwei Liu, Yong Zhao, Wenhao Ren, Xianjue Chen, Sheng Chen, Chuan Zhao (2020)
Metal-sulfur linkages achieved by organic tethering of Ru nanocrystals for enhanced electrochemical nitrogen reduction.Angewandte Chemie
-
Zhijian Wan, Youkun Tao, Jing Shao, Yinghui Zhang, Hengzhi You (2021)
Ammonia as an effective hydrogen carrier and a clean fuel for solid oxide fuel cellsEnergy Conversion and Management, 228
-
Bryan Suryanto, K. Matuszek, Jaecheol Choi, Rebecca Hodgetts, H. Du, Jacinta Bakker, Colin Kang, P. Cherepanov, A. Simonov, D. Macfarlane (2021)
Nitrogen reduction to ammonia at high efficiency and rates based on a phosphonium proton shuttleScience, 372
-
Yong Han, S. Axnanda, E. Crumlin, R. Chang, B. Mao, Z. Hussain, P. Ross, Yimin Li, Zhi Liu (2017)
Observing the Electrochemical Oxidation of Co Metal at the Solid/Liquid Interface Using Ambient Pressure X-ray Photoelectron Spectroscopy.The journal of physical chemistry. B, 122 2
-
Yuting Wang, Yifu Yu, Ranran Jia, Chao Zhang, Bin Zhang (2019)
Electrochemical synthesis of nitric acid from air and ammonia through waste utilizationNational Science Review, 6
-
C. Zamfirescu, I. Dincer (2008)
Using ammonia as a sustainable fuelJournal of Power Sources, 185
-
Xi‐ming Qu, Lin‐fan Shen, Yu-Jie Mao, Jin-Xia Lin, Yu-Yang Li, Guang Li, Yuyang Zhang, Yan‐xia Jiang, Shigang Sun (2019)
Facile Preparation of Carbon Shells-coated O-doped Molybdenum Carbide Nanoparticles as High Selective Electrocatalysts for Nitrogen Reduction Reaction under Ambient Conditions.ACS applied materials & interfaces
-
G. Kresse, J. Furthmüller (1996)
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis setComputational Materials Science, 6
-
D. De, J. Englehardt, E. Kalu (2000)
Electroreduction of nitrate and nitrite ion on a platinum-group-metal catalyst-modified carbon fiber electrode. Chronoamperometry and mechanism studiesJournal of The Electrochemical Society, 147
-
J. Yang, Haifeng Qi, Anqi Li, Xiaoyan Liu, Xiaofeng Yang, Shengxin Zhang, Qiaoyun Zhao, Qike Jiang, Yang Su, LeiLei Zhang, Jian-feng Li, Z. Tian, Wei Liu, Aiqin Wang, Tao Zhang (2022)
Potential-Driven Restructuring of Cu Single Atoms to Nanoparticles for Boosting the Electrochemical Reduction of Nitrate to Ammonia.Journal of the American Chemical Society
-
J. Nash, Xuan Yang, Jacob Anibal, M. Dunwell, S. Yao, K. Attenkofer, Jingguang Chen, Yushan Yan, Bingjun Xu (2019)
Elucidation of the Active Phase and Deactivation Mechanisms of Chromium Nitride in the Electrochemical Nitrogen Reduction ReactionThe Journal of Physical Chemistry C
-
J. Nørskov, J. Rossmeisl, and Logadottir, L. Lindqvist, J. Kitchin, T. Bligaard, H. Jónsson (2004)
Origin of the Overpotential for Oxygen Reduction at a Fuel-Cell CathodeJournal of Physical Chemistry B, 108
-
Nikifar Lazouski, Z. Schiffer, Kindle Williams, Karthish Manthiram (2019)
Understanding Continuous Lithium-Mediated Electrochemical Nitrogen ReductionJoule
-
L. Lietti, M. Daturi, V. Blasin-Aubé, G. Ghiotti, F. Prinetto, P. Forzatti (2012)
Relevance of the Nitrite Route in the NOx Adsorption Mechanism over Pt–Ba/Al2O3 NOx Storage Reduction Catalysts Investigated by using Operando FTIR SpectroscopyChemCatChem, 4
-
H. Heenen, Joseph Gauthier, H. Kristoffersen, T. Ludwig, Karen Chan (2020)
Solvation at metal/water interfaces: An ab initio molecular dynamics benchmark of common computational approaches.The Journal of chemical physics, 152 14
-
G. Henkelman, B. Uberuaga, H. Jónsson (2000)
A climbing image nudged elastic band method for finding saddle points and minimum energy pathsJournal of Chemical Physics, 113
-
Na Cao, Zengxi Wei, Jie Xu, Jun Luo, Anxiang Guan, A. Al-Enizi, Jianmin Ma, Gengfeng Zheng (2020)
Electrochemical nitrogen fixation via bimetallic Sn-Ti sites on defective titanium oxide catalysts.Journal of colloid and interface science, 588
-
C. Christensen, T. Johannessen, R. Sørensen, J. Nørskov (2006)
Towards an ammonia-mediated hydrogen economy?Catalysis Today, 111
-
Zhen-Yu Wu, M. Karamad, Xue Yong, Qizheng Huang, D. Cullen, Peng Zhu, Chuan Xia, Q. Xiao, Mohsen Shakouri, Feng-Yang Chen, Jung Kim, Yang Xia, Kimberly Heck, Yongfeng Hu, M. Wong, Qilin Li, I. Gates, Samira Siahrostami, Haotian Wang (2021)
Electrochemical ammonia synthesis via nitrate reduction on Fe single atom catalystNature Communications, 12
-
Nikifar Lazouski, Minju Chung, Kindle Williams, Michal Gala, Karthish Manthiram (2020)
Non-aqueous gas diffusion electrodes for rapid ammonia synthesis from nitrogen and water-splitting-derived hydrogenNature Catalysis, 3
-
Yuhang Wang, Aoni Xu, Ziyun Wang, Linsong Huang, Jun Li, Fengwang Li, Joshua Wicks, Mingchuan Luo, Dae-Hyun Nam, Chih-Shan Tan, Yu Ding, Jiawen Wu, Yanwei Lum, C. Dinh, D. Sinton, Gengfeng Zheng, E. Sargent (2020)
Enhanced nitrate-to-ammonia activity on copper-nickel alloys via tuning of intermediate adsorption.Journal of the American Chemical Society
-
Xianbiao Fu, Xingang Zhao, Xiaobing Hu, K. He, Yanan Yu, Tao Li, Qing Tu, Xin Qian, Qin Yue, M. Wasielewski, Yijin Kang (2020)
Alternative route for electrochemical ammonia synthesis by reduction of nitrate on copper nanosheetsApplied Materials Today, 19
-
Increasing Current Density of Li-Mediated Ammonia Synthesis with High Surface Area Copper Electrodes -
Wenyi Li, Ke Li, Y. Ye, Shengbo Zhang, Yanyan Liu, Guozhong Wang, C. Liang, Haimin Zhang, Huijun Zhao (2021)
Efficient electrocatalytic nitrogen reduction to ammonia with aqueous silver nanodotsCommunications Chemistry, 4
-
Jie Li, Guangming Zhan, Jianhua Yang, Fengjiao Quan, Chengliang Mao, Yang Liu, Bo Wang, F. Lei, Lejing Li, Alice Chan, Liangpang Xu, Yanbiao Shi, Yi Du, W. Hao, P. Wong, Jianfang Wang, S. Dou, Lizhi Zhang, Jimmy Yu (2020)
Efficient Ammonia Electrosynthesis from Nitrate on Strained Ruthenium Nanoclusters.Journal of the American Chemical Society
-
Barry Smith, R. Richards, W. Newton (2004)
Catalysts for Nitrogen Fixation -
Xiaohui Deng, Yongpeng Yang, Lei Wang, Xianzhu Fu, Jingli Luo (2021)
Metallic Co Nanoarray Catalyzes Selective NH3 Production from Electrochemical Nitrate Reduction at Current Densities Exceeding 2 A cm−2Advanced Science, 8
-
M. Biesinger, L. Lau, A. Gerson, R. Smart (2010)
Resolving surface chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Sc, Ti, V, Cu and ZnApplied Surface Science, 257
-
K. Mathew, V. Kolluru, Srinidhi Mula, Stephan Steinmann, Richard Hennig (2016)
Implicit self-consistent electrolyte model in plane-wave density-functional theory.The Journal of chemical physics, 151 23
-
G. Kresse, J. Hafner (1994)
Norm-conserving and ultrasoft pseudopotentials for first-row and transition elementsJournal of Physics: Condensed Matter, 6
-
Gaofeng Chen, Yifei Yuan, Hai‐Long Jiang, S. Ren, Liang‐Xin Ding, Lu Ma, Tianpin Wu, Jun Lu, Haihui Wang (2020)
Electrochemical reduction of nitrate to ammonia via direct eight-electron transfer using a copper–molecular solid catalystNature Energy, 5
-
Lin Li, A. Larsen, N. Romero, V. Morozov, C. Glinsvad, F. Abild-Pedersen, J. Greeley, K. Jacobsen, J. Nørskov (2013)
Investigation of Catalytic Finite-Size-Effects of Platinum Metal Clusters.The journal of physical chemistry letters, 4 1
-
I. Katsounaros, G. Kyriacou (2007)
Influence of the concentration and the nature of the supporting electrolyte on the electrochemical reduction of nitrate on tin cathodeElectrochimica Acta, 52
-
(2017)
www.advenergymat.de www.advancedsciencenews.com 2204236 -
Lin Hu, A. Khaniya, Jun Wang, Gang Chen, W. Kaden, Xiaofeng Feng (2018)
Ambient Electrochemical Ammonia Synthesis with High Selectivity on Fe/Fe Oxide CatalystACS Catalysis
-
Aayush Singh, Brian Rohr, Jay Schwalbe, M. Cargnello, Karen Chan, T. Jaramillo, I. Chorkendorff, J. Nørskov (2017)
Electrochemical Ammonia Synthesis-The Selectivity ChallengeACS Catalysis, 7
-
M. Dortsiou, G. Kyriacou (2009)
Electrochemical reduction of nitrate on bismuth cathodesJournal of Electroanalytical Chemistry, 630
-
Yuting Wang, Wei Zhou, Ranran Jia, Yifu Yu, Bin Zhang (2020)
Unveiling the Activity Origin of Copper-based Electrocatalyst for Selective Nitrate Reduction to Ammonia.Angewandte Chemie
-
Xuan Yang, J. Nash, Jacob Anibal, M. Dunwell, Shyam Kattel, E. Stavitski, K. Attenkofer, Jingguang Chen, Yushan Yan, Bingjun Xu (2018)
Mechanistic Insights into Electrochemical Nitrogen Reduction Reaction on Vanadium Nitride Nanoparticles.Journal of the American Chemical Society, 140 41
-
A. Klerke, C. Christensen, J. Nørskov, T. Vegge (2008)
Ammonia for hydrogen storage: challenges and opportunitiesJournal of Materials Chemistry, 18
-
J. Martínez, A. Ortiz, I. Ortiz (2017)
State-of-the-art and perspectives of the catalytic and electrocatalytic reduction of aqueous nitratesApplied Catalysis B-environmental, 207
-
(2022)
Boosting the electrochemical nitrogen reduction by rhenium-doping modulated TiO2 nanofibers -
Ji Li, Yuan Zhang, Chao Liu, Limin Zheng, E. Petit, K. Qi, Yang Zhang, Hua-Kun Wu, Wensen Wang, A. Tiberj, Xuechuan Wang, M. Chhowalla, L. Lajaunie, Ruohan Yu, D. Voiry (2021)
3.4% Solar‐to‐Ammonia Efficiency from Nitrate Using Fe Single Atomic Catalyst Supported on MoS2 NanosheetsAdvanced Functional Materials, 32
-
Shawn Lin, A. Gluhoi, B. Nieuwenhuys (2004)
Ammonia oxidation over Au/MOx/γ-Al2O3—activity, selectivity and FTIR measurementsCatalysis Today, 90
-
Chen Li, Ruizhi Xu, S. Ma, Yuhua Xie, Konggang Qu, Haifeng Bao, Weiwei Cai, Zehui Yang (2021)
Sulfur vacancies in ultrathin cobalt sulfide nanoflowers enable boosted electrocatalytic activity of nitrogen reduction reactionChemical Engineering Journal
-
Nishithan Kani, Aditya Prajapati, Brianna Collins, J. Goodpaster, Meenesh Singh (2020)
Competing Effects of pH, Cation Identity, H2O Saturation, and N2 Concentration on the Activity and Selectivity of Electrochemical Reduction of N2 to NH3 on Electrodeposited Cu at Ambient ConditionsACS Catalysis
-
M. Shipman, M. Symes (2017)
Recent progress towards the electrosynthesis of ammonia from sustainable resourcesCatalysis Today, 286
-
Jin-Xun Liu, D. Richards, Nirala Singh, B. Goldsmith (2019)
Activity and Selectivity Trends in Electrocatalytic Nitrate Reduction on Transition MetalsACS Catalysis
-
M. Nazemi, Sajanlal Panikkanvalappil, M. El-Sayed (2018)
Enhancing the rate of electrochemical nitrogen reduction reaction for ammonia synthesis under ambient conditions using hollow gold nanocagesNano Energy
-
Jacinto Sá, J. Anderson (2008)
FTIR study of aqueous nitrate reduction over Pd/TiO2Applied Catalysis B-environmental, 77
-
H. Du, M. Chatti, Rebecca Hodgetts, P. Cherepanov, C. Nguyen, K. Matuszek, D. Macfarlane, A. Simonov (2022)
Electroreduction of nitrogen with almost 100% current-to-ammonia efficiencyNature, 609
-
G. Henkelman, H. Jónsson (2000)
Improved tangent estimate in the nudged elastic band method for finding minimum energy paths and saddle pointsJournal of Chemical Physics, 113
-
A. Holleman, E. Wiberg, N. Wiberg (2001)
Inorganic Chemistry -
(1992)
News - Perkin-Elmer Corp., Opt -
K. Mathew, R. Sundararaman, Kendra Letchworth-Weaver, T. Arias, R. Hennig (2013)
Implicit solvation model for density-functional study of nanocrystal surfaces and reaction pathways.The Journal of chemical physics, 140 8
-
J. Yang, Hongwei Liu, W. Martens, R. Frost (2010)
Synthesis and Characterization of Cobalt Hydroxide, Cobalt Oxyhydroxide, and Cobalt Oxide NanodiscsJournal of Physical Chemistry C, 114
-
Bryan Suryanto, H. Du, Dabin Wang, Jun Chen, A. Simonov, D. Macfarlane (2019)
Challenges and prospects in the catalysis of electroreduction of nitrogen to ammoniaNature Catalysis, 2
-
J. Erisman, M. Sutton, J. Galloway, Z. Klimont, W. Winiwarter (2008)
How a century of ammonia synthesis changed the worldNature Geoscience, 1
-
Joshua McEnaney, S. Blair, A. Nielander, Jay Schwalbe, David Koshy, M. Cargnello, T. Jaramillo (2020)
Electrolyte Engineering for Efficient Electrochemical Nitrate Reduction to Ammonia on a Titanium ElectrodeACS Sustainable Chemistry & Engineering, 8
-
Ping Zhang, Wei Xiong, Min Zhou (2020)
Effect of nickel oxide morphology on the nitrogen electrochemical reduction reaction, 2
-
Jaecheol Choi, H. Du, C. Nguyen, Bryan Suryanto, A. Simonov, D. Macfarlane (2020)
Electroreduction of Nitrates, Nitrites, and Gaseous Nitrogen Oxides: A Potential Source of Ammonia in Dinitrogen Reduction StudiesACS energy letters, 5
-
Chencheng Dai, Yuanmiao Sun, Gao Chen, A. Fisher, Zhichuan Xu (2020)
Electrochemical Oxidation of Nitrogen towards Direct Nitrate Production on Spinel Oxides.Angewandte Chemie
-
M. Biesinger, B. Payne, L. Lau, A. Gerson, R. Smart (2009)
X‐ray photoelectron spectroscopic chemical state quantification of mixed nickel metal, oxide and hydroxide systemsSurface and Interface Analysis, 41
-
Tieliang Li, Shuhe Han, Changhong Wang, Yanmei Huang, Yuting Wang, Yifu Yu, Bin Zhang (2021)
Ru-Doped Pd Nanoparticles for Nitrogen Electrooxidation to NitrateACS Catalysis
- Publisher
- Wiley
- Copyright
- © 2023 Wiley‐VCH GmbH
- ISSN
- 1614-6832
- eISSN
- 1614-6840
- DOI
- 10.1002/aenm.202204236
- Publisher site
- See Article on Publisher Site
Abstract
NO3− is a prominent waste byproduct in ammunition industries, and valorization of NO3− into NH3 is desired. NH3 synthesized from waste using renewable energy could be used as an energy storage medium. For such a process, higher selectivity, stability, and enhanced activity per unit mass of catalyst is required. This work reports CoO nanoclusters functionalized on graphene as an efficient catalyst for electrochemical NO3− reduction to NH3 with >98% NH3 Faradaic efficiency and an NH3 current density (geometric) of ≈400 mA cm−2. A highest NH3 yield of 25.63 mol g−1 h−1 is obtained. The developed catalyst prevents the NN coupling step which is required for promoting the selectivity of NH3 over N2. Density functional theory calculations reveal that CoO NC/graphene has similar selectivity to that of polycrystalline Co and that higher activity can be obtained with lower catalyst loading.
Journal
Advanced Energy Materials – Wiley
Published: May 1, 2023
Keywords: electrochemical ammonia synthesis; electrochemical nitrate reduction; nitrate removal; solar‐to‐ammonia efficiency